5%Carbowax 20M Carbopack B填充柱 顶空气相色谱测定大气污染物中甲醇含量

名称：填充柱

色谱固定液：5%聚乙二醇
载体：石墨炭黑80-120目

规格：2m*3mm，2m*1/8

型号：5%Carbowax 20M Carbopack B

应用： HJ T33-1999 固定污染源排气中甲醇的测定气相色谱法

 适用范围

1.1 本标准适用于固定污染源有组织排放和无组织排放的甲醇测定。

1.2 以3倍噪音色谱峰高值计算，当色谱进样量为1.0 ml时，方法的检出限为2 mg/m³；定量测定的浓度范围为5.0-10⁴ mg/m³。

2 方法原理
      载气携带含有甲醇(CH₃OH）的试样通过装有固定相的色谱柱，流出色谱柱的甲醇由氢火焰离子化检测器(FID)测定。以标准样品色谱峰的保留时间进行定性，以峰高（或峰面积）定量。

浩瀚色谱（山东）应用技术开发有限公司首先使用纯水为吸收液,吸收空气中的甲醇,再采用顶空气相色谱法分析吸收液中甲醇浓度,由此建立了自动顶空5%Carbowax 20M Carbopack B填充柱气相色谱法测定空气和废气中甲醇的方法,并对自动顶空进样条件进行了优化。结果表明,当采样体积为24 L、吸收液体积5 mL时,该方法的低检出浓度为0.1 mg/m3,相对标准偏差为2.1%～5.3%,加标回收率为95%～108%。该法操作简单,具有较好的灵敏度和的准确度,自动化程度高,可连续完成样品的前处理、样品进样和色谱分析。


顶空气相色谱测定大气污染物中甲醇含量  测试谱图：


Determination of Methanol in Air Pollutants by Headspace Gas Chromatography
Determination of Methanol in Air Pollutants by Headspace Gas Chromatography Details:

Name: Packed Column

Chromatographic fixative: 5% polyethylene glycol
Carrier: graphite carbon black 80-120 mesh

Specifications: 2m*3mm, 2m*1/8

Model: 5%Carbowax 20M Carbopack B

Application: HJ T33-1999 Determination of methanol in exhaust gas from stationary pollution sources by gas chromatography



 Scope of application

1.1 This standard is applicable to the determination of methanol in organized and unorganized emissions from stationary pollution sources.

1.2 Calculated by 3 times the noise chromatographic peak height, when the chromatographic injection volume is 1.0 ml, the detection limit of the method is 2 mg/m3; the concentration range of quantitative determination is 5.0-104 mg/m3.

2 Principles of the method
      The carrier gas carries a sample containing methanol (CH3OH) through a chromatographic column equipped with a stationary phase, and the methanol flowing out of the chromatographic column is detected by a hydrogen flame ionization detector (FID). Qualitative by the retention time of the standard sample chromatographic peak, quantitative by peak height (or peak area).

Haohan Chromatography (Shandong) Application Technology Development Co., Ltd. first used pure water as the absorption liquid to absorb methanol in the air, and then used headspace gas chromatography to analyze the methanol concentration in the absorption liquid, thus establishing an automatic headspace 5% Carbowax 20M Carbopack B. A method for the determination of methanol in air and waste gas by packed-column gas chromatography, and the automatic headspace injection conditions were optimized. The results show that when the sampling volume is 24 L and the absorption liquid volume is 5 mL, the minimum detection concentration of this method is 0.1 mg/m3, the relative standard deviation is 2.1%-5.3%, and the recovery rate of standard addition is 95%-108% . The method is simple to operate, has good sensitivity and reliable accuracy, and has a high degree of automation. It can continuously complete sample pretreatment, sample injection and chromatographic analysis.


Determination of methanol content in air pollutants by headspace gas chromatography Test spectrum: